Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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Chloride ions react with silver I ions argenntometric give the insoluble silver chloride:. The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction.

You can review the results of that calculation in Table 9. The first type of indicator is a species that forms a precipitate with the titrant.

Home Questions Tags Users Unanswered. This is the same example that we used in developing the calculations for a precipitation titraations curve. At the beginning of this section we noted that the first precipitation titration used the cessation of precipitation to signal the end point.

Before the end point, the precipitate of AgCl has a negative surface charge due to the adsorption of excess Cl —. Calcium acetate “fixes” free chlorine, precipitates carbonates, and neutralizes the resultant solution. Because CrO 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of K 2 CrO 4 is added.

Argentometric (silver nitrate) titrations overview

Post as a guest Name. We call this type of titration a precipitation titration. Anionic dyes such as dichlorofluorescein are attracted to the particles, and undergo a colour change upon adsorption, representing the end-point.

What about argentometric titration? By using this site, you agree to the Terms of Use and Privacy Policy. The end point is found by visually examining the titration curve. A better fit is possible if the two points before the equivalence point are further apart—for example, 0 mL and 20 mL— and the two points after the equivalence point are further apart. The sample contains 0. Carbonates and phosphates precipitate with silver, and need to be absent to prevent inaccurate results.


The red points corresponds to the data in Table 9. An example of a lab procedure is here 2. In the Mohr method, named after Karl Friedrich Mohrpotassium chromate is an indicator, giving red silver chromate after all chloride ions have reacted:. It is also possible to use indirect argentometric methods for determination of anions, that create insoluble salts with silver I for example phosphate PO4, arsenate AsO4 and chromate CrO4.

In analytical chemistryargentometry is a type of titration involving the silver I ion. Views Read Edit View history. The sample solution is titrated against a solution of silver nitrate of known concentration. These methods are based on back titration of excess silver with standardized thiocyanate solution. A further discussion of potentiometry is found in Chapter A comparison of our sketch to the exact titration curve Figure 9. Methods based on precipitation of silver compounds I are called collectively argentometric methods.

The concentration of unreacted Cl — after adding A simple equation takes advantage of the fact that the sample contains only KCl and NaBr; thus. Post Your Answer Discard By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.

Note This is the same example that we used in developing the calculations for a precipitation titration curve. See the text for additional details.


By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies.

The Fajans method was first published in the s by Kasimir Fajans. In this section we demonstrate a simple method for sketching a precipitation titration curve. Because this equation has two unknowns—g KCl and g NaBr—we need another equation that includes both unknowns. Like, we use alkalimetric titration to calculate the real concentration of table vinegar.

It is not suitable arbentometric titrating against chloride anions because it binds to AgCl more strongly than chloride does.


For tjtrations, after adding What are some example of the use of argentometric titration? Ferric acetate removes phosphates. The solution needs to be near neutral, because silver hydroxide forms at high pH, while the chromate forms H 2 CrO 4 at low pH, reducing the concentration of chromate ions, and delaying the formation of the precipitate. Note See Table 9.

They are most often used for determination of chloride ions, but they can be used also for other halides bromide, iodide and some pseudohalides thiocyanate. By now you are familiar with our approach to calculating a titration curve. To calculate the concentration of Cl — we use the K sp expression for AgCl; thus.

To find the moles of titrant reacting with the sample, we first need to correct for the reagent blank; thus. A second type of indicator uses a species that forms a colored complex with the titrant or the titrand. A blank titration requires 0.